Can my stepbrother see me without hijab?

No, a stepbrother is not a mahram, so you wear hijab in front of him. A stepbrother (your stepparent's son from another relationship) is not related to you by blood, marriage or breastfeeding in a way that forbids marriage. A half-brother, who shares a parent with you, is different: he is a mahram.
Who counts as a mahram
Your mahrams are the men you can never marry. The Quran lists the women forbidden in marriage, starting with close blood relatives:
The list goes on to aunts, nieces, milk relatives, mothers-in-law and stepdaughters, and the next verse says the rest are lawful. Stepsiblings aren't on it. For the full picture, see Who can see me without my hijab?
Stepbrother vs half-brother
- Half-brother (same mother or same father): a real brother in Islamic law, so he is a mahram.
- Stepbrother (no shared parent): not a mahram. In Islam, the two of you could even marry each other.
- Milk brother (you were breastfed by the same woman as a baby, within the conditions scholars set): a mahram.
Living in the same house
Blended families are common in the UK, Europe and the USA, and many converts share a home with a stepbrother. That can feel awkward, but it's manageable:
- Wear hijab and modest clothes in shared spaces like the kitchen and living room.
- Your bedroom is your private space; you can uncover there with the door closed.
- Avoid being alone together for long stretches behind closed doors. The Prophet ﷺ warned men about entering upon women who aren't their mahram, and even said of in-law relatives, "The in-law is death" (Sahih al-Bukhari 5232), meaning close relatives who aren't mahram need the most care because people relax around them.
Keep the relationship kind
Not being a mahram doesn't mean being cold. You can chat, eat together as a family and be polite and helpful. If your family doesn't understand why you cover around him, explain gently that it's about Islamic rules, not about distrusting him. For similar family questions, see Do I have to wear hijab at home? and Can I hug my relatives at holiday gatherings as a Muslim?
- A stepbrother is not a mahram; keep hijab on around him.
- A half-brother or milk brother is a mahram.
- Your own room is where you can relax uncovered.
- Avoid long private time alone, but stay friendly.
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